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Appearance:White powder
Throughput:100|Kilogram|Day
pd_productuse:intermediate
Delivery Time:instock
Purity:98%
Product Name: (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL
CAS: 100165-88-6
MF: C48 H40 P2
MW: 678.78
EINECS: 1312995-182-4
Melting point 252-256 °C
alpha -160° (c 0.5, C6H6)
Boiling point 754.4±60.0 °C(Predicted)
form Powder
color White
optical activity [α]20/D -156°, c = 0.5 in benzene
Water Solubility Insoluble in water.
InChIKey IOPQYDKQISFMJI-UHFFFAOYSA-N
Reaction
Useful ligand for palladium-catalyzed carbon-oxygen bond formation.
Ligand for palladium-catalyzed α-arylation of ketones.
Ligand for Cu-catalyzed asymmetric conjugate reduction.
Ligand for Cu-catalyzed asymmetric dienolate addition to aldehydes.
Enantioselective conjugate reduction of lactones and lactams.
Ligand used in the enantioselective cycloaddition of allenylsilanes with α-Imino esters.
Catalytic Aldol reaction to ketones.
Ligand with rhodium catalyses [2+2+2] cycloaddition reaction of alkenes and alkynes.
Ligand used in the iridium-catalyzed enantioselective C-H bond activation of 2-(alkylamino)-pyridine with alkenes.
Iridium-catalyzed regio-, diastereo-, and enantioselective tert-(hydroxyl)-prenylation of alcohols.
Rhodium-catalyzed cross cyclotrimerization.
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