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677-22-5

Product Name:tert-butylmagnaeium chloride
Molecular Formula:C₄H₉ClMg
Appearance:clear faint grey to grey, grey-brown or light

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Product Details

Appearance:clear faint grey to grey, grey-brown or light

Purity:99%

High Quality tert-butylmagnaeium chloride 677-22-5 Supply, Best Price

677-22-5 Name
Name	tert-butylmagnaeium chloride
Synonym	tert-Butylmagnesium chloride, 1M in MeTHF;tert-Butylmagnesium chloride [1.0 M solution in THF];tert-Butylmagnesium chloride, 1,7M solution in diethyl ether, AcroSeal§3;tert-Butylmagnesium chloride, 1.7M solution in THF, AcroSeal;tert-Butylmagnesium chloride, 1.7M solution in diethyl ether, AcroSeal;tert-ButylMagnesiuM chloride ,1.0 M in tetrahydrofuran;tert-butylMagnesiuM;(1,1-Dimethylethyl)magnesium chloride

677-22-5 Chemical & Physical Properties
Melting point	46ºC to 50ºC
Density	0.931 g/mL at 25 °C
Molecular Formula	C4H9ClMg
Molecular Weight	116.87200
Flash Point	34 °F
LogP	2.44360
Exact Mass	116.02400
Storage condition	2-8°C

tert-butylmagnaeium chloride 677-22-5 Usage

Tert-butylmagnesium chloride (tBuMgC1) is a Grignard reagent used in organic synthesis. It is also involved in copper-catalyzed cross-coupling reaction with primary-alkyl halides. tert-Butylmagnesium chloride could even be used as the initial nucleophile to afford the highly sterically hindered S-tert-butyl sulfoximine 2v in 53% yield; such products have previously been prepared by three sequential deprotonations/methylations of an S-methyl sulfoximine.

InChI:InChI=1/C4H9.ClH.Mg/c1-4(2)3;;/h1-3H3;1H;/q;;+1/p-1/rC4H9Mg.ClH/c1-4(2,3)5;/h1-3H3;1H/q+1;/p-1

677-22-5 Relevant articles

Radical and ionic polymerization of vinyl chloride with tert‐butylmagnesium chloride

A Guyot, J Mordini

Journal of Polymer Science Part C: Polymer Symposia, Volume33, Issue1 1971 Pages 65-73

The earlier results concerning the kinetics of polymerization and initiator consumption, molecular weight distribution, and the nature of the chain ends in the polymerization of vinyl chloride initiated by tert-butylmagnesium chloride (tBuMgCl) in tetrahydrofuran and other solvents are rediscussed in terms of the simultaneous participation of an ionic mechanism and a radical mechanism.

Synthetic methods and reactions. 146. Olefins from crowded carbonyl compounds with tert-butyllithium (tert-butylmagnesium chloride)/thionyl chloride. Study of carbocationic reaction intermediates and rearrangement-cleavage under stable ion conditions using carbon-13 NMR spectroscopy

George A. Olah, An Hsiang Wu, Omar Farooq, and G. K. Surya Prakash

J. Org. Chem. 1990, 55, 6, 1792–1796

In the study of the dehydration of di-tert-butylmethyl alcohol to give trimethylethylene through elimination of a tert-butyl group (as isobutylene), Crowded carbonyl compounds when reacted with tert-butyllithium or tert-butylmagnesium chloride followed by thionyl chloridetreatment give in a one-pot reaction olefins.