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768-95-6

  • Product Name:1-Adamantanol
  • Molecular Formula:C10H16O
  • Appearance:white to off-white crystalline powder or needles
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Product Details

Appearance:white to off-white crystalline powder or needles

Purity:99%

High Quality 1-Adamantanol 768-95-6 with Good Price

768-95-6 Name

Name

1-Adamantanol

Synonym

TRICYCLO[3.3.1.1(3,7)]DECAN-1-OL;TRICYCLO[3.3.1.1]DECAN-1-OL;1-HYDROXYDIAMANTANE;1-HYDROXYADAMANTANE;1-AD-OH;1-ADA-OH;1-ADAMANTANOL;1-Adamantol

 

768-95-6 Chemical & Physical Properties

Melting point 

247 °C (subl.)(lit.)

Boiling point

245.8±8.0 °C at 760 mmHg

Density

1.2±0.1 g/cm3

Molecular Formula

C10H16O

Molecular Weight

152.233

Flash Point

101.1±10.9 °C

PSA

20.23000

LogP

2.16

Exact Mass

152.120117

Vapour Pressure

0.0±1.1 mmHg at 25°C

Index of Refraction

1.581

Storage condition

2-8°C

High Quality 1-Adamantanol 768-95-6 Usage

1-adamantanol is also known as 1-hydroxide adamantane, 1-tricyclo [3.3.1.1 (3.7)] decyl alcohol. At room temperature, it is white crystalline powder with the melting point higher than 240 ℃. It is soluble in organic solvents and insoluble in water with sublimation property. It can be used for the manufacture of synthetic adamantane derivatives and adapalene. 1-Adamantanol was used in the preparation of 1,3-adamantanediol. It is used in the manufacture of synthetic adamantane derivatives and adapalene. If 2-adamantanol is a suspected impurity, then dissolve the substance (10g) in acetone (100mL) and add Jones's reagent [CrO3 (10.3g) in H2O (30mL)], then conc H2SO4 (8.7mL) is added dropwise (turns green in colour) until excess reagent is present (slight red colour). 

InChI:InChI=1/C10H16O/c11-10-4-7-1-8(5-10)3-9(2-7)6-10/h7-9,11H,1-6H2

768-95-6 Relevant articles

Thermochemistry of Bridged-ring Substances. Enthalpies of Formation of Diamantan-1-, -3-, and -4-ol and of Diamantanone

Clark, Timothy,Knox, Trevor McO.,McKervey, M. Anthony,Mackle, Henry

, p. 1686 - 1689 (1980)

The enthalpies of combustion and of sublimation four mono-oxygenated diamantanes have been determined. Comparisons are made between the experimental gas-phase enthalpies of formation and those obtained by molecular mechanics (empirical force field) calculations based on the Allinger MM1 force field model.

Aprotic diazotization of endo-7-aminomethylbicyclo[3,3,1]nonan-3-one

Liu, Jih-Hua,Kovacic, Peter

, p. 564a (1972)

Aprotic diazotization of endo-7-aminomethylbicyclo[3,3,1]nonan-3-one yields protoadamantan-4-one and 3-methylbicyclo[3,3,1]non-2-en-7-one; the latter was converted into adamantan-1-ol on catalytic hydrogenation with Pd-C.

768-95-6 Process route

adamantane
281-23-2

adamantane

1-adamanthanol
768-95-6

1-adamanthanol

1-adamantanol
700-57-2

1-adamantanol

benzaldehyde
100-52-7

benzaldehyde

benzyl alcohol
100-51-6,185532-71-2

benzyl alcohol

Conditions
Conditions Yield
With meso-tetraphenylporphyrin iron(III) chloride; peroxyphenylacetic acid; In benzene; at 25 ℃; for 0.166667h; Product distribution; other alkane; other peroxy acid; also var. iron(III) porphyrin-deriv. - ligand complexes;
61%
7%
acetonitrile
75-05-8,26809-02-9

acetonitrile

trans-N,N'-bis(1-adamantyl)diazene
24325-56-2

trans-N,N'-bis(1-adamantyl)diazene

1,1'-Biadamantane
3732-31-8

1,1'-Biadamantane

1-adamanthanol
768-95-6

1-adamanthanol

N-(1-adamantyl)acetamide
880-52-4

N-(1-adamantyl)acetamide

1-acetyladamantane
1660-04-4

1-acetyladamantane

Conditions
Conditions Yield
With thianthrenium perchlorate; Further byproducts given; Ambient temperature;
90%
2.5%
0.6%
5.5%

768-95-6 Upstream products

  • 768-90-1
    768-90-1

    1-Adamantyl bromide

  • 110-86-1
    110-86-1

    pyridine

  • 281-23-2
    281-23-2

    adamantane

  • 67-56-1
    67-56-1

    methanol

768-95-6 Downstream products

  • 828-51-3
    828-51-3

    1-Adamantanecarboxylic acid

  • 935-56-8
    935-56-8

    1-chloroadamantane

  • 880-52-4
    880-52-4

    N-(1-adamantyl)acetamide

  • 5854-52-4
    5854-52-4

    1-adamantyl chloroformate

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