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14495-51-3

  • Product Name:Benzene,1-bromo-4-chloro-2-methyl-
  • Molecular Formula:C7H6BrCl
  • Appearance:Clear colourless to slightly orange liquid
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Product Details

Appearance:Clear colourless to slightly orange liquid

Purity:99%

High Purity 1-Bromo-4-chloro-2-methylbenzene 14495-51-3

14495-51-3 Name

Name

1-Bromo-4-chloro-2-methylbenzene

Synonym

Benzene,1-bromo-4-chloro-6-methyl-;Toluene, 2-bromo-5-chloro-;5-CHLORO-2-BROMOTOLUENE;6-BROMO-3-CHLOROTOLUENE;2-BROMO-5-CHLOROTOLUENE;1-BROMO-4-CHLORO-2-METHYLBENZENE;2-BROMO-5-CHLOROTOLUENE 99%;2-Bromo-5-Chlorotolune98%

 

14495-51-3 Chemical & Physical Properties

Boiling point

219.1±20.0 °C at 760 mmHg

Density

1.5±0.1 g/cm3

Molecular Formula

C7H6BrCl

Molecular Weight

205.480

Flash Point

95.6±0.0 °C

LogP

3.98

Exact Mass

203.934128

Vapour Pressure

0.2±0.4 mmHg at 25°C

Index of Refraction

1.566

Water Solubility

INSOLUBLE

1-Bromo-4-chloro-2-methylbenzene 14495-51-3 Liquid Usage

1-Bromo-4-chloro-2-methylbenzene 14495-51-3 is CLEAR COLOURLESS TO SLIGHTLY ORANGE LIQUID. It has been used in the preparation of 4-chloro-2-methylbenzophenone.

InChI:InChI=1/C7H6BrCl/c1-5-4-6(9)2-3-7(5)8/h2-4H,1H3

14495-51-3 Relevant articles

Dichloro-Bis(aminophosphine) Complexes of Palladium: Highly Convenient, Reliable and Extremely Active Suzuki–Miyaura Catalysts with Excellent Functional Group Tolerance

Jeanne L. Bolliger, Christian M. Frech Dr.

Chemistry–A European Journal, Volume16, Issue13 April 6, 2010 Pages 4075-4081

Excellent conversion rates, product yields, and selectivities were also found for other halides, for example, 1-bromo-4-chloro-2-methylbenzene, 1-bromo-2,6-dichlorobenzene…Dichloro-bis(aminophosphine) complexes are stable depot forms of palladium nanoparticles and have proved to be excellent Suzuki–Miyaura catalysts. Simple modifications of the ligand (and/or the addition of water to the reaction mixture) have allowed their formation to be controlled.

Highly efficient Sandmeyer reaction on immobilized CuI/CuII-based catalysts

Tarkhanova, Irina G.,Gantman, Michail G.,Sigeev, Alexander S.,Maslakov, Konstantin I.,Zelikman, Vladimir M.,Beletskaya, Irina P.

, p. 261 - 263 (2018/06/01)

Highly effective embodiment of Sandmeyer reaction has been revealed for Cu-based catalysts incorporating ionic liquid on Silochrom support. The most active catalyst (TOF = = 4000–8000 h–1) contains comparable amounts of cuprous and cupric chloride anions. The reported method allows one to carry out the reaction for anilines in the one-pot mode.

14495-51-3 Process route

1-chloro-3-methylbenzene
108-41-8

1-chloro-3-methylbenzene

2-bromo-5-chlorotoluene
14495-51-3

2-bromo-5-chlorotoluene

m-Chlorobenzaldehyde
587-04-2

m-Chlorobenzaldehyde

Conditions
Conditions Yield
With potassium permanganate; alkyl carboxylic acid; corresponding anhydride; potassium bromide; Yield given. Yields of byproduct given; Heating;
 
amino-5-bromo-2-toluene
6933-10-4

amino-5-bromo-2-toluene

2-bromo-5-chlorotoluene
14495-51-3

2-bromo-5-chlorotoluene

Conditions
Conditions Yield
amino-5-bromo-2-toluene; With boron trifluoride diethyl etherate; tetraethylammonium chloride; In acetonitrile; at 0 ℃; for 0.166667h;
With tert.-butylnitrite; In acetonitrile; at 0 - 20 ℃; for 1h;
90%

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