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14495-51-3

Product Name:Benzene,1-bromo-4-chloro-2-methyl-
Molecular Formula:C₇H₆BrCl
Appearance:Clear colourless to slightly orange liquid

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Product Details

Appearance:Clear colourless to slightly orange liquid

Purity:99%

High Purity 1-Bromo-4-chloro-2-methylbenzene 14495-51-3

14495-51-3 Name
Name	1-Bromo-4-chloro-2-methylbenzene
Synonym	Benzene,1-bromo-4-chloro-6-methyl-;Toluene, 2-bromo-5-chloro-;5-CHLORO-2-BROMOTOLUENE;6-BROMO-3-CHLOROTOLUENE;2-BROMO-5-CHLOROTOLUENE;1-BROMO-4-CHLORO-2-METHYLBENZENE;2-BROMO-5-CHLOROTOLUENE 99%;2-Bromo-5-Chlorotolune98%

14495-51-3 Chemical & Physical Properties
Boiling point	219.1±20.0 °C at 760 mmHg
Density	1.5±0.1 g/cm3
Molecular Formula	C7H6BrCl
Molecular Weight	205.480
Flash Point	95.6±0.0 °C
LogP	3.98
Exact Mass	203.934128
Vapour Pressure	0.2±0.4 mmHg at 25°C
Index of Refraction	1.566
Water Solubility	INSOLUBLE

1-Bromo-4-chloro-2-methylbenzene 14495-51-3 Liquid Usage

1-Bromo-4-chloro-2-methylbenzene 14495-51-3 is CLEAR COLOURLESS TO SLIGHTLY ORANGE LIQUID. It has been used in the preparation of 4-chloro-2-methylbenzophenone.

InChI:InChI=1/C7H6BrCl/c1-5-4-6(9)2-3-7(5)8/h2-4H,1H3

14495-51-3 Relevant articles

Dichloro-Bis(aminophosphine) Complexes of Palladium: Highly Convenient, Reliable and Extremely Active Suzuki–Miyaura Catalysts with Excellent Functional Group Tolerance

Jeanne L. Bolliger, Christian M. Frech Dr.

Chemistry–A European Journal, Volume16, Issue13 April 6, 2010 Pages 4075-4081

Excellent conversion rates, product yields, and selectivities were also found for other halides, for example, 1-bromo-4-chloro-2-methylbenzene, 1-bromo-2,6-dichlorobenzene…Dichloro-bis(aminophosphine) complexes are stable depot forms of palladium nanoparticles and have proved to be excellent Suzuki–Miyaura catalysts. Simple modifications of the ligand (and/or the addition of water to the reaction mixture) have allowed their formation to be controlled.

Highly efficient Sandmeyer reaction on immobilized CuI/CuII-based catalysts

Tarkhanova, Irina G.,Gantman, Michail G.,Sigeev, Alexander S.,Maslakov, Konstantin I.,Zelikman, Vladimir M.,Beletskaya, Irina P.

, p. 261 - 263 (2018/06/01)

Highly effective embodiment of Sandmeyer reaction has been revealed for Cu-based catalysts incorporating ionic liquid on Silochrom support. The most active catalyst (TOF = = 4000–8000 h–1) contains comparable amounts of cuprous and cupric chloride anions. The reported method allows one to carry out the reaction for anilines in the one-pot mode.

14495-51-3 Process route

: 108-41-8
1-chloro-3-methylbenzene

: 14495-51-3
2-bromo-5-chlorotoluene

: 587-04-2
m-Chlorobenzaldehyde

Conditions

Conditions	Yield
With potassium permanganate; alkyl carboxylic acid; corresponding anhydride; potassium bromide; Yield given. Yields of byproduct given; Heating;

: 6933-10-4
amino-5-bromo-2-toluene

: 14495-51-3
2-bromo-5-chlorotoluene

Conditions

Conditions	Yield
amino-5-bromo-2-toluene; With boron trifluoride diethyl etherate; tetraethylammonium chloride; In acetonitrile; at 0 ℃; for 0.166667h; With tert.-butylnitrite; In acetonitrile; at 0 - 20 ℃; for 1h;	90%